2023, 42(3): 9-14.
doi: 10.12390/jbr2022121
Abstract:
【Objective】In order to study the effects of different proportions of modifiers, glacial acetic acid concentration, treatment time and temperature on the bending strength, tensile strength and hardness of bamboo, to measure the changes of bending strength, tensile strength and hardness before and after modification, soa s to obtain the appropriate pencil plate treatment technology. 【Method】Bamboo was used as raw material and impregnated with glacial acetic acid and hydrogen peroxide. The chemical composition and modification effect of modified bamboo were characterized by XRD, FTIR and TG. 【Result】The bending strength and tensile strength of modified bamboo decreased with the increase of temperature, glacial acetic acid and hydrogen peroxide content, respectively. Compared with the control group, the bending strength and tensile strength of modified bamboo decreased by 44.5%, 59.9% and 44.81% respectively. The peak pyrolysis temperature of TG and DTG lagged behind, and the residue rate decreased, indicating that the content of glacial acetic acid increased, and some cellulose and hemicellulose were decomposed. XRD analysis showed that the crystallinity of modified bamboo decreased by about 1.5%, and the crystallinity decreases with the increase of treatment temperature. The enhancement of methyl and carboxyl absorption peaked at 1 250-1 377 cm-1 and hydroxyl absorption peaked at 3 415 cm-1 indicated the increase of hydrophilic groups in bamboo. 【Conclusion】 The optimal modifier concentration ratio was 1∶1, treatment temperature was 60 ℃, and treatment time was 24 hours.